Rubin Kazan slays the Champions
Rubin Kazan silenced the Nou Camp just two minutes into their Champions League clash with Barcelona as the holders slipped to a shock 2-1 defeat.
Alexander Ryazantsev's 35-yard rocket gave the Russians the lead in the Group F encounter - and left Barca trailing for the first time this season.
Zlatan Ibrahimovic levelled in the 48th minute, controlling the ball on his chest and firing home via a post, but there was another twist to come as Gokdeniz Karadeniz grabbed a 73rd-minute winner.
Another major upset looked on the cards at the San Siro as Dynamo Kiev twice led against Inter Milan only for Jose Mourinho's men to fight back to draw 2-2.
Taras Mykhalyk put Dynamo Kiev in front after five minutes and Lucio powered a header into his own net to restore their lead after Dejan Stankovic had levelled.
But Walter Samuel headed in at the right end two minutes after the break to make it 2-2.
Barca, Rubin and Dynamo are now all level on four points, with Inter bottom of the pool on three.
In Group E Fiorentina are three points behind leaders Lyon after a 4-3 win away to Debrecen.
There was a flying start in Hungary between Debrecen and Fiorentina as the Italian side led 2-1 after 10 minutes and 4-2 at half-time.
Peter Czvitkovics put Debrecen in front after two minutes but a brace from Adrian Mutu either side of an Alberto Gilardino effort put the visitors 3-1 in front.
Gergely Rudolf struck a second for the home side before Mario Santana scored the sixth goal of the half in the 37th minute.
There was only one goal in the second period, Adamo Coulibaly netting two minutes from time to bring Debrecen to within one of Fiorentina, but the Italians claimed the win.
Sevilla won 3-1 at Stuttgart to extend their 100% record in Group G and strengthen their position at its summit.
Sebastien Squillaci scored twice either side of a Jesus Navas goal as the visitors took command of the match before Elson scored a consolation for Markus Babbel's men.
In Group H Ieroklis Stoltidis headed an injury-time winner for Olympiacos as they came from behind to beat Standard Liege 2-1 and strengthen their position in second behind the Gunners.
Igor De Camargo scored first for the Belgian side before Kostas Mitroglou levelled two minutes before the break.
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